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Issue 10, 2020
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There is nothing wrong with being soft: using sulfur ligands to increase axiality in a Dy(iii) single-ion magnet

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Abstract

A new air-stable sulfur-ligated Dy(III) single-ion magnet has been successfully isolated with Ueff = 638 K and hysteresis loops open up to 7 K. In silico studies show that the S co-ligands significantly boost the axiality and that Te- and Se-donors have the potential to further enhance the magnetic properties.

Graphical abstract: There is nothing wrong with being soft: using sulfur ligands to increase axiality in a Dy(iii) single-ion magnet

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Supplementary files

Article information


Submitted
17 Sep 2019
Accepted
23 Dec 2019
First published
26 Dec 2019

This article is Open Access

Chem. Commun., 2020,56, 1533-1536
Article type
Communication

There is nothing wrong with being soft: using sulfur ligands to increase axiality in a Dy(III) single-ion magnet

A. B. Canaj, S. Dey, O. Céspedes, C. Wilson, G. Rajaraman and M. Murrie, Chem. Commun., 2020, 56, 1533
DOI: 10.1039/C9CC07292F

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