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Issue 1, 2020
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Mass spectrometric detection of enantioselectivity in three-component complexation, copper(ii)-chiral tetradentate ligand-free amino acid in solution

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Abstract

By using electrospray ionization mass spectrometry coupled with the use of deuterium-labelled quasienantiomers, enantioselective coordination of a free amino acid as the second ligand of a copper(II) complex with a novel chiral tetradentate ligand was evaluated quantitatively in a short measurement time.

Graphical abstract: Mass spectrometric detection of enantioselectivity in three-component complexation, copper(ii)-chiral tetradentate ligand-free amino acid in solution

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Article information


Submitted
15 Sep 2019
Accepted
01 Nov 2019
First published
11 Nov 2019

Chem. Commun., 2020,56, 54-57
Article type
Communication

Mass spectrometric detection of enantioselectivity in three-component complexation, copper(II)-chiral tetradentate ligand-free amino acid in solution

T. Nakakoji, H. Sato, D. Ono, H. Miyake, S. Shinoda, H. Tsukube, H. Kawasaki, R. Arakawa and M. Shizuma, Chem. Commun., 2020, 56, 54
DOI: 10.1039/C9CC07231D

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