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Issue 48, 2019
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Hybridization-activated new deep ultraviolet transparent nonlinear optical material Ba11[Al(PO4)4](P2O7)(PO4)3 with balanced overall performance and parsimony-forbidden structure

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Abstract

A new nonlinear optical material, Ba11[Al(PO4)4](P2O7)(PO4)3, was rationally synthesized via the hybridization of three types of anionic groups, namely [AlO4]5−, [PO4]3− and [P2O7]4−, via a spontaneous nucleation method. Ba11[Al(PO4)4](P2O7)(PO4)3 was characterized with high thermal stability, deep ultraviolet transparency and moderate second-order optical nonlinearity, which were favourable for practical applications.

Graphical abstract: Hybridization-activated new deep ultraviolet transparent nonlinear optical material Ba11[Al(PO4)4](P2O7)(PO4)3 with balanced overall performance and parsimony-forbidden structure

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Article information


Submitted
15 Oct 2019
Accepted
18 Nov 2019
First published
20 Nov 2019

J. Mater. Chem. C, 2019,7, 15162-15165
Article type
Communication

Hybridization-activated new deep ultraviolet transparent nonlinear optical material Ba11[Al(PO4)4](P2O7)(PO4)3 with balanced overall performance and parsimony-forbidden structure

Z. Fang, B. Yang, C. Hu and J. Mao, J. Mater. Chem. C, 2019, 7, 15162
DOI: 10.1039/C9TC05648C

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