Hybridization-activated new deep ultraviolet transparent nonlinear optical material Ba11[Al(PO4)4](P2O7)(PO4)3 with balanced overall performance and parsimony-forbidden structure

Zhi Fang; Bingping Yang; Chunli Hu; Jianggao Mao

doi:10.1039/C9TC05648C

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Hybridization-activated new deep ultraviolet transparent nonlinear optical material Ba₁₁[Al(PO₄)₄](P₂O₇)(PO₄)₃ with balanced overall performance and parsimony-forbidden structure†

Zhi Fang,

^a Bingping Yang,

^a Chunli Hu^a and Jianggao Mao

*^a

Author affiliations

* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
E-mail: mjg@fjirsm.ac.cn

Abstract

A new nonlinear optical material, Ba₁₁[Al(PO₄)₄](P₂O₇)(PO₄)₃, was rationally synthesized via the hybridization of three types of anionic groups, namely [AlO₄]⁵⁻, [PO₄]³⁻ and [P₂O₇]⁴⁻, via a spontaneous nucleation method. Ba₁₁[Al(PO₄)₄](P₂O₇)(PO₄)₃ was characterized with high thermal stability, deep ultraviolet transparency and moderate second-order optical nonlinearity, which were favourable for practical applications.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C9TC05648C
Article type: Communication
Submitted: 15 Oct 2019
Accepted: 18 Nov 2019
First published: 20 Nov 2019

Download Citation

J. Mater. Chem. C, 2019,7, 15162-15165

Permissions

Request permissions

Hybridization-activated new deep ultraviolet transparent nonlinear optical material Ba₁₁[Al(PO₄)₄](P₂O₇)(PO₄)₃ with balanced overall performance and parsimony-forbidden structure

Z. Fang, B. Yang, C. Hu and J. Mao, J. Mater. Chem. C, 2019, 7, 15162 DOI: 10.1039/C9TC05648C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Journal of Materials Chemistry C