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Issue 47, 2019
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Significant enhancement in the thermoelectric performance of Bi2O2S through dimensionality reduction

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Abstract

Nano-engineered technology has been applied in thermoelectrics for the enhanced performance owing to the substantial thermal conductivity reduction. Based on density functional theory, the electronic and phonon transport properties of the Bi2O2S bulk and two-dimensional (2D) nano-thin film are systematically studied. Due to the typical layered structure, the thermoelectric properties of bismuth chalcogenides Bi2O2S vary greatly along different axes showing strong anisotropy. It was found that the dimensionality reduction in the Bi2O2S bulk could not only avoid the poor thermoelectric effect in the interlayer direction, but also notably reduce the intralayer lattice thermal conductivity from the bulk value of 2.9 W m−1 K−1 to nearly 1.85 W m−1 K−1 at 300 K. The average ZT value of the Bi2O2S monolayer could reach 3.4 at 700 K. Meanwhile, the thermoelectric conversion efficiency of the nano-thin film could be improved by 75% compared with that of the bulk material. Our theoretical results prove that low-dimensional nanostructure technology could be an effective approach to enhance the thermoelectric conversion efficiency of materials.

Graphical abstract: Significant enhancement in the thermoelectric performance of Bi2O2S through dimensionality reduction

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Publication details

The article was received on 22 Aug 2019, accepted on 29 Oct 2019 and first published on 18 Nov 2019


Article type: Paper
DOI: 10.1039/C9TC04648H
J. Mater. Chem. C, 2019,7, 14986-14992

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    Significant enhancement in the thermoelectric performance of Bi2O2S through dimensionality reduction

    R. Zhang, Z. Zhou, N. Qi, B. Zhao, Q. Zhang, Z. Zhang and Z. Chen, J. Mater. Chem. C, 2019, 7, 14986
    DOI: 10.1039/C9TC04648H

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