Revealing the nature of photoluminescence emission in the metal-halide double perovskite Cs2AgBiBr6

Abstract

Double perovskite crystals such as Cs₂AgBiBr₆ are expected to overcome the limitation of classic hybrid organic–inorganic perovskite crystals related to the presence of lead and the lack of structural stability. Perovskites are ionic crystals in which the carriers are expected to strongly couple to lattice vibrations. In this work we demonstrate that the photoluminescence (PL) emission in Cs₂AgBiBr₆ is strongly influenced by the strong electron–phonon coupling. Combining photoluminescence excitation (PLE) and Raman spectroscopy we show that the PL emission is related to a color center rather than a band-to-band transition. The broadening and the Stokes shift of the PL emission from Cs₂AgBiBr₆ is well explained using a Franck–Condon model with a Huang–Rhys factor of S = 11.7 indicating a strong electron–phonon interaction in this material.