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Indicator/Catalyst Displacement Assay: Design of a Latent Catalyst for the Selective Detection and Degradation of Cyanide by Prussian Blue Analog-Modified TiO2 Nanoparticles

Abstract

Prussian blue bimetallic analog (PBA)-modified TiO2 particles (NP1–3) were explored as a new generation of latent catalytic materials for the simultaneous detection and removal of cyanide using the indicator/catalytic displacement approach (ICDA). These PBAs not only act as the ‘colored coats’ but also quench the oxidative degradation properties of TiO2 by facilitating the recombination of its electrons and holes. The obtained results revealed that among common organic/inorganic pollutants (e.g., cyanide, aniline, 1,5-naphthalenedisulfonic acid, benzoic acid, and 4-nitrophenol), only CN− could selectively induce a colorimetric response and the photocatalytic oxidative degradation of TiO2, while analytes bearing amine, sulfate, carboxylate, and phenol functionalities did not induce any response. These functional materials were also found to be applicable in real water bodies.

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Publication details

The article was received on 21 Jan 2019, accepted on 09 May 2019 and first published on 13 May 2019


Article type: Paper
DOI: 10.1039/C9TC00368A
J. Mater. Chem. C, 2019, Accepted Manuscript

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    Indicator/Catalyst Displacement Assay: Design of a Latent Catalyst for the Selective Detection and Degradation of Cyanide by Prussian Blue Analog-Modified TiO2 Nanoparticles

    C. Shen, A. Zheng, M. Huang, Q. Tang, C. Gong and C. F. Chow, J. Mater. Chem. C, 2019, Accepted Manuscript , DOI: 10.1039/C9TC00368A

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