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AIE-active difluoroboronated acylhydrozone dyes (BOAHY) emitting across the entire visible region and their photo-switching properties

Abstract

A new family of difluoroboronate anchored acylhydrozones, named BOAHY, have been developed as green fluorescent protein (GFP) chromophore analogues via a simple one-pot two-step reaction in moderate to good yields. They were well characterized by NMR, HRMS, X-ray crystal structural and various spectroscopic techniques. These BOAHYs are weakly fluorescent in their solutions but emit brightly in the powder and film states across the entire visible region, with a maximum fluorescence quantum yield of 62%. They also exhibit notable aggregation-induced emission (AIE)-active features. Photoisomerization transformation under the irradiation of strong UV light at 365 nm as well as the viscosity-dependent fluorescence changes, indicate that the restriction of the intramolecular free rotation of the single bonds at the periphery is the main cause for the novel AIE process of these BOAHYs. In addition, the Z/E photoisomerization was studied for its potential applications as photoswitching materials. UV light irradiation at 365 nm caused obvious fluorescence changes, and the photoisomerization was found to be reversible in a dark environment, which paves a new way for creating fluorescent photoswitches based on these planar conformations.

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Publication details

The article was received on 16 Jan 2019, accepted on 06 Feb 2019 and first published on 06 Feb 2019


Article type: Paper
DOI: 10.1039/C9TC00316A
Citation: J. Mater. Chem. C, 2019, Accepted Manuscript

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    AIE-active difluoroboronated acylhydrozone dyes (BOAHY) emitting across the entire visible region and their photo-switching properties

    C. Yu, E. Hao, X. Fang, Q. Wu, L. Wang, J. Li, L. Xu, L. Jiao and W. R. Wong, J. Mater. Chem. C, 2019, Accepted Manuscript , DOI: 10.1039/C9TC00316A

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