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Temperature-induced transport changes in molecular junctions based on a spin crossover complex

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Abstract

This work describes the study of molecular junctions embedding the spin crossover complex [Fe(H2B(pz)2)2(phen)] as an active switchable thin film. In these junctions we observed that the spin state conversion causes a gradual increase in the current density, which may be due to a crossover from direct tunneling to multi-step hopping.

Graphical abstract: Temperature-induced transport changes in molecular junctions based on a spin crossover complex

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Publication details

The article was received on 28 Dec 2018, accepted on 05 Apr 2019 and first published on 05 Apr 2019


Article type: Communication
DOI: 10.1039/C8TC06587J
Citation: J. Mater. Chem. C, 2019, Advance Article

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    Temperature-induced transport changes in molecular junctions based on a spin crossover complex

    L. Poggini, M. Gonidec, R. K. Canjeevaram Balasubramanyam, L. Squillantini, G. Pecastaings, A. Caneschi and P. Rosa, J. Mater. Chem. C, 2019, Advance Article , DOI: 10.1039/C8TC06587J

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