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An antimonene/Cp*Rh(phen)Cl/black phosphorus hybrid nanosheet-based Z-scheme artificial photosynthesis for enhanced photo/bio-catalytic CO2 reduction

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Abstract

Developing a biocatalyzed artificial photosynthesis system (APS) with a Z-scheme for CO2 conversion has a promising outlook. However, it remains unexplored and challenging. Herein, we present an antimonene (AM) and black phosphorus (BP) hybrid nanosheet (HNSs) based Z-scheme APS for enhanced photo/bio-catalytic CO2 reduction. An “amphipathic” polymer PEI-PEG-C18 with a positively charged PEI-head and hydrophobic C18-tail was synthesized and further modified with an electron mediator (M, Cp*Rh(phen)Cl). Using this PEI-PEG-C18-M as a “double-side tap”, AM/M/BP HNS-based Z-scheme photocatalytic systems were constructed through catenating AM NSs via a hydrophobic interaction with the hydrophobic C18-tail and subsequent BP NSs via electrostatic interactions with the positively charged PEI-head. Thereafter, the biocatalytic system, including NAD(H)+ and redox enzymes, were sandwiched between the AM and BP layers through an electrostatic attraction with the amide groups in the “double-side tap”. Due to the high separation efficiency of the photogenerated electrons and holes and the improved reduction and oxidation potentials, the integrated Z-scheme APS shows excellent performance. In particular, although neither AM nor BP could catalyze NADH regeneration using H2O as an electron donor under visible light, a 35 ± 4% regeneration of NADH and 160 ± 24 μmol formic acid production were achieved by the AM/M/BP HNS-based Z-scheme APS. Moreover, the compatibility and omnipotence of the HNS-based APS for the synthesis of other high value-added products from CO2 have been demonstrated through assembling the corresponding biocatalysts.

Graphical abstract: An antimonene/Cp*Rh(phen)Cl/black phosphorus hybrid nanosheet-based Z-scheme artificial photosynthesis for enhanced photo/bio-catalytic CO2 reduction

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Publication details

The article was received on 10 Oct 2019, accepted on 21 Nov 2019 and first published on 27 Nov 2019


Article type: Paper
DOI: 10.1039/C9TA11167K
J. Mater. Chem. A, 2020, Advance Article

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    An antimonene/Cp*Rh(phen)Cl/black phosphorus hybrid nanosheet-based Z-scheme artificial photosynthesis for enhanced photo/bio-catalytic CO2 reduction

    X. Ji, Y. Kang, T. Fan, Q. Xiong, S. Zhang, W. Tao and H. Zhang, J. Mater. Chem. A, 2020, Advance Article , DOI: 10.1039/C9TA11167K

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