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Issue 44, 2019
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Earth abundant, non-toxic, 3D printed Cu2−xS with high thermoelectric figure of merit

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Abstract

The toxicity, earth abundance and manufacturing costs of thermoelectric materials are three leading reasons why thermoelectric generators are not used in wide scale applications. This is the first paper to tackle all three of these problems simultaneously. A pseudo-3D printing technique is combined with Cu2−xS based inks to yield bulk samples capable of being used in traditional architecture thermoelectric generators. These bulk samples are characterised over a wide temperature range in XPS, which reveals a curing temperature of 550 K yields pure Cu2−xS samples. The thermoelectric properties of these samples are tested over a wide temperature range, with a peak ZT of 0.63 ± 0.09 being recorded at 966 K. This work gives a significant advancement towards low cost highly efficient non-toxic thermoelectric generators. This work also provides the first route to print Cu2−xS, a material of much interest to the solar cell, catalysis and biosensor fields.

Graphical abstract: Earth abundant, non-toxic, 3D printed Cu2−xS with high thermoelectric figure of merit

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Publication details

The article was received on 11 Sep 2019, accepted on 25 Oct 2019 and first published on 29 Oct 2019


Article type: Paper
DOI: 10.1039/C9TA10064D
J. Mater. Chem. A, 2019,7, 25586-25592
  • Open access: Creative Commons BY license
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    Earth abundant, non-toxic, 3D printed Cu2−xS with high thermoelectric figure of merit

    M. R. Burton, S. Mehraban, J. McGettrick, T. Watson, N. P. Lavery and M. J. Carnie, J. Mater. Chem. A, 2019, 7, 25586
    DOI: 10.1039/C9TA10064D

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      [Original citation] - Published by The Royal Society of Chemistry.

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