In-situ TEM Investigation of Electron Beam Induced Ultrafast Chemical Lithiation for Charging
The enhancement of operational life and charging speed have been considered two of the major factors that will influence the development of energy storage devices in the future. Here, we utilized an electron beam (e-beam) to retrieve the Li metals from LiF, the degradation product of LiPF6, and trigger the further lithiation of NiFe2O4/carbon nanotubes (CNTs) to relieve the degradation of the electrolyte and gain ultrafast lithiation. Accordingly, in situ transmission electron microscopy (in situ TEM) was used to investigate the comprehensive mechanism of the whole process. The e-beam acting on the degradation product LiF clusters led to the generation of Li flakes, which served as the source for the subsequent lithiation. Then, with these Li flakes, the chemical lithiation of NiFe2O4/CNTs was triggered, resulting in the phase transformation to Ni and Fe nanograins. Compared to “electrochemical” lithiation, the ultrafast reaction speed and the ability to charge without directly applied potential in the “chemical” lithiation has the ability to extend to more diverse applications. Through this investigation, we provide a new strategy for designing novel energy storage devices for the energy-harvesting field.