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Thermally induced top-down nanostructuring for the synthesis of a core/shell-structured CoO/CoSx electrocatalyst

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Abstract

Many bottom-up nanostructuring approaches have benefitted the research field of electrocatalysis by significantly increasing the catalytic activity of electrocatalysts. In general, however, they require tedious wet chemistry steps and delicate control while managing considerable surface energies. In addition, they often suffer from scalability issues. As part of an effort to address these issues, we developed a simple two-step thermal route to produce a nanostructured electrocatalyst with high catalytic activity from its bulk form. In this work, we demonstrate the preparation of core/shell CoO/CoSx from bulk Co3O4 as a case study. Our novel approach uses a low-temperature thermal treatment under NH3 and a subsequent treatment in a H2S atmosphere, judiciously exploiting the unique features of each reaction atmosphere. Hot NH3 treatment reduces Co3O4 to CoO, during which a significant lattice mismatch between the Co3O4 and CoO fractures crystallites, and the coalescence of oxygen vacancies introduces porosity. Subsequent H2S treatment specifically forms electrocatalytically active CoSx species on the surface of CoO. We explore the use of the resulting nanostructured CoO/CoSx as an alternative to state-of-the-art noble metal catalysts in the triiodide reduction and oxygen evolution reactions, finding that its activity is comparable to those of standard catalysts. Given the simplicity and scalability of this innovative low-temperature reaction concept, we anticipate that the present demonstration will open new avenues for the synthesis of highly active electrocatalysts.

Graphical abstract: Thermally induced top-down nanostructuring for the synthesis of a core/shell-structured CoO/CoSx electrocatalyst

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Publication details

The article was received on 22 Aug 2019, accepted on 27 Oct 2019 and first published on 30 Oct 2019


Article type: Paper
DOI: 10.1039/C9TA09229C
J. Mater. Chem. A, 2019, Advance Article

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    Thermally induced top-down nanostructuring for the synthesis of a core/shell-structured CoO/CoSx electrocatalyst

    M. S. Kim, M. A. Abbas, R. Thota and J. H. Bang, J. Mater. Chem. A, 2019, Advance Article , DOI: 10.1039/C9TA09229C

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