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Pyrite-type ruthenium disulfide with tunable disorder and defect enables ultra-efficient overall water splitting

Abstract

The exploration of efficient electrocatalysts for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is significant for water splitting associated with the storage of clean and renewable energy. Here, we report a simple and scalable low-temperature sulfuration method to achieve simultaneous modulation of disorder and defects in pyrite-type RuS2 nanoparticles to dramatically enhance the HER and OER catalytic activity. The disordered structure can increase the electrochemical active surface area, while the defect engineering can effectively regulate the electronic structure and thus improve the intrinsic activity, as revealed by combined experimental and theoretical density functional theory (DFT) investigations. Through controllable disorder and defect engineering, the optimized RuS2-500 catalysts (with sulfuration temperature of 500 °C) supportred on glass carbon electrode exhibits ultra-efficient bifunctional electrocatalytic activity with η-10=78 mV for HER and η10=282 mV for OER, superior to the various Ru-based and pyrite-type catalysts. Remarkably, when used as both the anode and the cathode in an alkaline water electrolyzer, RuS2-500 delivers 10 mA cm-2 at an ultralow cell voltage of 1.527 V with long-term stability, outperforming the benchmark Pt/C//RuO2 couple and most state-of-the-art overall-water-splitting electrocatalysts ever reported. This work thus provides a new and facile way for improving the catalytic activity through a synergistic modulation strategy.

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Supplementary files

Publication details

The article was received on 19 Apr 2019, accepted on 17 May 2019 and first published on 17 May 2019


Article type: Paper
DOI: 10.1039/C9TA04120F
J. Mater. Chem. A, 2019, Accepted Manuscript

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    Pyrite-type ruthenium disulfide with tunable disorder and defect enables ultra-efficient overall water splitting

    Y. Zhu, H. Tahini, Y. Wang, Q. Lin, C. Doherty, Y. Liang, Y. Liu, X. Li, J. Lu, S. C. Smith, C. Selomulya, X. Zhang, Z. Shao and H. Wang, J. Mater. Chem. A, 2019, Accepted Manuscript , DOI: 10.1039/C9TA04120F

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