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Bis[di(4-methoxyphenyl)amino]carbazole-capped indacenodithiophenes as hole transport materials for highly efficient perovskite solar cells: the pronounced positioning effect of a donor group on the cell performance

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Abstract

Bis[di(4-methoxyphenyl)amino]carbazole-capped indacenodithiophenes (IDTs) have been constructed as hole transport materials (HTMs) for perovskite solar cells (PSCs). Two IDT-based HTMs, one with 3,6-bis[di(4-methoxyphenyl)amino]carbazole (YK1) and another with 2,7-bis[di(4-methoxyphenyl)amino]carbazole (YK2), show different performances in PSCs. The PSC device based on YK1 displays a very impressive PCE of 20.13% under AM1.5G solar illumination, which is much higher than those of the devices based on YK2 (17.35%) and Spiro-OMeTAD (19.01%) under the same working conditions. This is mainly because YK1 has more effective intermolecular π–π stacking, a lower-lying HOMO level and higher hole-mobility than YK2 and Spiro-OMeTAD. Furthermore, the YK1-based PSC exhibits excellent long-term stability retaining 94% of the initial PCE value after a 600 h lifetime without encapsulation owing to its better film morphology and hydrophobicity. These findings would shed light on the crucial importance of molecular engineering and allow its extension into general principles for the design of new HTMs for highly efficient and stable PSCs.

Graphical abstract: Bis[di(4-methoxyphenyl)amino]carbazole-capped indacenodithiophenes as hole transport materials for highly efficient perovskite solar cells: the pronounced positioning effect of a donor group on the cell performance

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Publication details

The article was received on 15 Feb 2019, accepted on 29 Mar 2019 and first published on 29 Mar 2019


Article type: Communication
DOI: 10.1039/C9TA01731C
Citation: J. Mater. Chem. A, 2019, Advance Article

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    Bis[di(4-methoxyphenyl)amino]carbazole-capped indacenodithiophenes as hole transport materials for highly efficient perovskite solar cells: the pronounced positioning effect of a donor group on the cell performance

    Y. Hua, S. Chen, D. Zhang, P. Xu, A. Sun, Y. Ou, T. Wu, H. Sun, B. Cui and X. Zhu, J. Mater. Chem. A, 2019, Advance Article , DOI: 10.1039/C9TA01731C

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