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Rechargeable metal batteries based on selenium cathodes: progress, challenges and perspectives

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Abstract

Rechargeable metal batteries using selenium or selenide as the cathodes have attracted considerable attention during the past few years owing to selenium/selenide possessing a high volumetric energy density that is comparable to that of sulfur, a moderate output voltage and characteristics of environmental benignity. However, the applications of Se-based rechargeable metal batteries are hindered by the easy dissolution of polyselenides with severe instances of the shuttle phenomenon, poor cycle life and coulombic efficiency, low loading and low utilization of active materials, as well as the relatively high cost of selenium. To overcome these challenges, scientists have proposed various strategies, including optimizing electrode nanostructures, developing new electrolytes, and constructing novel battery structures. Herein, this review systematically introduces various nanostructured Se-based cathode materials, and new electrolytes and separators for Se-based rechargeable metal batteries, as well as investigating the electrochemistry of various Se-based rechargeable metal batteries and cell structure designs. We also present perspectives for future development in line with the preparation of high energy density, environmentally friendly and sustainable selenium-based energy storage systems.

Graphical abstract: Rechargeable metal batteries based on selenium cathodes: progress, challenges and perspectives

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Publication details

The article was received on 30 Dec 2018, accepted on 26 Mar 2019 and first published on 27 Mar 2019


Article type: Review Article
DOI: 10.1039/C8TA12537F
Citation: J. Mater. Chem. A, 2019, Advance Article

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    Rechargeable metal batteries based on selenium cathodes: progress, challenges and perspectives

    X. Gu, T. Tang, X. Liu and Y. Hou, J. Mater. Chem. A, 2019, Advance Article , DOI: 10.1039/C8TA12537F

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