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CoII-catalyzed room-temperature growth of MnO2 on the skeleton of carbonized zeolitic imidazolate framework-67 crystals for boosting oxygen reduction reaction

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Abstract

MnO2/C composites are widely used as cathode active materials or electrocatalysts in electrochemical power sources. Compared with a physical mixture of MnO2 and carbon materials, the growth of MnO2 on the surface of carbon can greatly improve the electrochemical performance of MnO2/C, and is usually performed at a temperature higher than 100 °C. From the viewpoint of sustainable development, the room-temperature growth of MnO2 on carbon would greatly reduce the cost and thermal pollution. Herein, at room temperature, we successfully planted MnO2 nanosheets over carbon particles, achieving MnO2/C composites through a redox reaction between MnO4 ions and carbonized zeolitic imidazolate framework-67 (ZIF-67) crystals (CZIF-67). Room-temperature growth of MnO2 may be attributed to the catalytic effect of CoII ions of Co3O4 nanoparticles formed during ZIF-67 carbonization. The resulting MnO2/CZIF-67 composites exhibit excellent catalytic performance towards the oxygen reduction reaction: the onset potential, the half-wave potential, and the electron transfer number are ∼0.88 V, ∼0.79 V and 3.6, respectively, which are close to the corresponding values of the state-of-the-art Pt/C. Also, the resulting MnO2/CZIF-67 shows better long-term durability and methanol tolerance than Pt/C, indicative of its potential applications in fuel cells and metal–air batteries.

Graphical abstract: CoII-catalyzed room-temperature growth of MnO2 on the skeleton of carbonized zeolitic imidazolate framework-67 crystals for boosting oxygen reduction reaction

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Publication details

The article was received on 04 Dec 2018, accepted on 29 Jan 2019 and first published on 29 Jan 2019


Article type: Paper
DOI: 10.1039/C8TA11658J
Citation: J. Mater. Chem. A, 2019, Advance Article

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    CoII-catalyzed room-temperature growth of MnO2 on the skeleton of carbonized zeolitic imidazolate framework-67 crystals for boosting oxygen reduction reaction

    J. Zhang, L. Zhou, J. Cheng, X. Yin, W. Kuang and Y. Li, J. Mater. Chem. A, 2019, Advance Article , DOI: 10.1039/C8TA11658J

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