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A metal–organic framework film with a switchable anodic and cathodic behaviour in a photo-electrochemical cell

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Abstract

Photo-active metal–organic frameworks (MOFs) are considered as promising materials for the study of photo-electrochemical cells (PECs). They can be utilized as porous, high surface area scaffolds for the assembly of molecular chromophores atop semiconducting electrodes. Usually, however, the lack of prominent electronic interactions between adjacent MOF-installed chromophores impedes the development of PECs based solely on MOFs (without the use of a semiconducting electrode, e.g. TiO2). Here we demonstrate that unlike standard semiconducting photo-electrodes, the photo-electrochemical behavior of a MOF-based electrode can be switched from photo-anodic to photo-cathodic by using appropriate redox mediators in the electrolyte. Additionally, a proof-of-principle photo-electrocatalytic H2 production using a MOF-based photo-cathode is provided. Thus, these findings have a clear impact on the design of MOF-based PECs for solar fuel generation.

Graphical abstract: A metal–organic framework film with a switchable anodic and cathodic behaviour in a photo-electrochemical cell

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Publication details

The article was received on 31 Oct 2018, accepted on 13 Nov 2018 and first published on 13 Nov 2018


Article type: Paper
DOI: 10.1039/C8TA10483B
Citation: J. Mater. Chem. A, 2019, Advance Article
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    A metal–organic framework film with a switchable anodic and cathodic behaviour in a photo-electrochemical cell

    R. Ifraemov, R. Shimoni, W. He, G. Peng and I. Hod, J. Mater. Chem. A, 2019, Advance Article , DOI: 10.1039/C8TA10483B

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