Jump to main content
Jump to site search


Stability progress of perovskite solar cells dependent on the crystalline structure: From 3D ABX3 to 2D Ruddlesden−Popper perovskite absorbers

Abstract

Among all types of photovoltaics, perovskite solar cells (PSCs) have received extensive attention because of their potential for achieving cheap, lightweight, facile and fast fabricated devices. Although the power conversion efficiency (PCE) of PSCs reached up to 23%, they are facing issues toward commercialization such as short lifetime. Remarkably, the most important key factors that regulate the durability of the devices are the type and crystalline structure of perovskite (PSK) materials. Though CH3NH3PbX3 is the first and also the widely utilized material as a light absorber in PSCs, it suffers from undesired moisture stability, structural phase alteration, and photo and thermal instabilities. In this regard, PSK crystal structure has been focused as a key factor to prolong the device lifetime. This review presents the progress of the change of the PSK structure from 3 dimensional CH3NH3PbX3 to mixed cations or halides based PSKs and finally to Ruddlesden−Popper PSK two dimensional (2D) homologous structures regarding the lifetime improvement. To obtain insight on a realistic path towards durable and commercially viable PSCs, it is shown how the crystal formation energy, hydrophobicity, interface of the grains, and structural phase strength have been tuned to overcome the lack of the durability in PSK devices and the current status.

Back to tab navigation

Publication details

The article was received on 30 Oct 2018, accepted on 21 Jan 2019 and first published on 23 Jan 2019


Article type: Review Article
DOI: 10.1039/C8TA10444A
Citation: J. Mater. Chem. A, 2019, Accepted Manuscript

  •   Request permissions

    Stability progress of perovskite solar cells dependent on the crystalline structure: From 3D ABX3 to 2D Ruddlesden−Popper perovskite absorbers

    F. Arabpour Roghabadi, M. Alidaei, S. M. Mousavi, T. ashjari, A. shokrolahzadeh Tehrani, V. Ahmadi and S. M. Sadrameli, J. Mater. Chem. A, 2019, Accepted Manuscript , DOI: 10.1039/C8TA10444A

Search articles by author

Spotlight

Advertisements