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Biphasic behaviors and regeneration energy of a 2-(diethylamino)-ethanol and 2-((2-aminoethyl)amino) ethanol blend for CO2 capture

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Abstract

High regeneration energy is one of the bottlenecks of traditional monoethanolamine (MEA) technology for CO2 capture. A novel process using a biphasic solvent is a potential solution towards a significant reduction in the regeneration energy. A 2-(diethylamino)-ethanol (DEEA) and 2-((2-aminoethyl)amino) ethanol (AEEA) blend is a promising biphasic solvent with high stability and low cost. The biphasic behavior of CO2 absorption in the DEEA/AEEA blend was investigated to optimize CO2 capacity and minimize the regeneration energy. 60% DEEA/20% AEEA is the optimal biphasic solvent with 60% higher CO2 capacity and 44% lower regeneration energy than that of the conventional MEA solvent. 13C NMR analysis was performed to reveal the phase separation mechanism. CO2 reaction products of amine carbamates and bicarbonate (HCO3/CO32−) accumulate in the CO2-rich phase while unreacted DEEA and AEEA migrate to the CO2-lean phase. Only sending the CO2-rich phase into the stripper enables to increase CO2 partial pressure and reduce the heat duty. On the other hand, a significant increase in the viscosity of the CO2-rich phase increases the energy penalty by decreasing the heat transfer coefficient of the heat exchanger. Due to the phase separation, the regeneration energy of the DEEA/AEEA biphasic solvent is less affected by the increased viscosity compared to other water-lean solvents. A normalized factor was proposed to incorporate both effects of increased viscosity and phase separation on the regeneration energy of the biphasic solvent.

Graphical abstract: Biphasic behaviors and regeneration energy of a 2-(diethylamino)-ethanol and 2-((2-aminoethyl)amino) ethanol blend for CO2 capture

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Publication details

The article was received on 19 Sep 2019, accepted on 13 Oct 2019 and first published on 14 Oct 2019


Article type: Paper
DOI: 10.1039/C9SE00821G
Sustainable Energy Fuels, 2019, Advance Article

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    Biphasic behaviors and regeneration energy of a 2-(diethylamino)-ethanol and 2-((2-aminoethyl)amino) ethanol blend for CO2 capture

    F. Liu, M. Fang, N. Yi, T. Wang and Q. Wang, Sustainable Energy Fuels, 2019, Advance Article , DOI: 10.1039/C9SE00821G

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