Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 27th March 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.

Issue 1, 2019
Previous Article Next Article

Effect of single metal doping on the thermoelectric properties of SnTe

Author affiliations


SnTe, a lead-free chalcogenide-based material, shows potential to achieve high thermoelectric performance. This report presents a comparative study of different metallic dopants in SnTe and their effect on its microstructures, and mechanical and thermoelectric properties. Doped SnTe (Sn1−xAxTe, A = Co, Ni, Zn, Ge, and x = 0.01, 0.03, 0.05) materials are prepared by melting–quenching synthesis followed by spark plasma sintering. X-ray powder diffraction analysis showed that the solubility of Co, Ni, and Zn in the structure is in the range from 0 to 0.01; however, Ge can be doped in higher amounts. The back-scattered electron images and elemental maps revealed that the CoTe, Ni3SnTe2 and ZnTe impurity phases precipitate on the grain boundaries in the SnTe matrix. Ge-doped samples have more uniform microstructures with a very few Ge-rich regions, which implies higher Ge solubility in agreement with the XRD results. The existence of impurity phases in the Co-, Ni-, and Zn-doped samples yields lower lattice thermal conductivities without deterioration in charge transport properties, leading to higher ZT values relative to the pristine SnTe sample. The microhardness of the doped samples is also improved due to the crack growth suppression and crack branching.

Graphical abstract: Effect of single metal doping on the thermoelectric properties of SnTe

Back to tab navigation

Publication details

The article was received on 27 Jul 2018, accepted on 06 Nov 2018 and first published on 06 Nov 2018

Article type: Paper
DOI: 10.1039/C8SE00385H
Citation: Sustainable Energy Fuels, 2019,3, 251-263

  •   Request permissions

    Effect of single metal doping on the thermoelectric properties of SnTe

    M. Aminzare, Y. Tseng, A. Ramakrishnan, K. Chen and Y. Mozharivskyj, Sustainable Energy Fuels, 2019, 3, 251
    DOI: 10.1039/C8SE00385H

Search articles by author