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Issue 34, 2019
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Three-component vicinal-diarylation of alkenes via direct transmetalation of arylboronic acids

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Abstract

Herein, we report three-component vicinal-diarylation of non-conjugated alkenes initiated by transmetalation of arylboronic acids, which provides complementary access to β,γ-diaryl carbonyl compounds. We have also screened a large number of chiral ligands for developing an enantioselective version of this reaction and obtained the preliminary results (up to 79 : 21 e.r.). Notably, the methodology developed herein represents the first three component syn-vicinal-dicarbofunctionalization of non-conjugated alkenes involving palladium catalysis.

Graphical abstract: Three-component vicinal-diarylation of alkenes via direct transmetalation of arylboronic acids

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Supplementary files

Article information


Submitted
05 May 2019
Accepted
03 Jul 2019
First published
03 Jul 2019

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2019,10, 7952-7957
Article type
Edge Article

Three-component vicinal-diarylation of alkenes via direct transmetalation of arylboronic acids

Y. Zhang, G. Chen and D. Zhao, Chem. Sci., 2019, 10, 7952
DOI: 10.1039/C9SC02182E

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