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Three-component vicinal-diarylation of alkenes via direct transmetalation of arylboronic acids

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Abstract

Herein, we report three-component vicinal-diarylation of non-conjugated alkenes initiated by transmetalation of arylboronic acids, which provides complementary access to β,γ-diaryl carbonyl compounds. We have also screened a large number of chiral ligands for developing an enantioselective version of this reaction and obtained the preliminary results (up to 79 : 21 e.r.). Notably, the methodology developed herein represents the first three component syn-vicinal-dicarbofunctionalization of non-conjugated alkenes involving palladium catalysis.

Graphical abstract: Three-component vicinal-diarylation of alkenes via direct transmetalation of arylboronic acids

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Publication details

The article was received on 05 May 2019, accepted on 03 Jul 2019 and first published on 03 Jul 2019


Article type: Edge Article
DOI: 10.1039/C9SC02182E
Chem. Sci., 2019, Advance Article
  • Open access: Creative Commons BY license
    All publication charges for this article have been paid for by the Royal Society of Chemistry

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    Three-component vicinal-diarylation of alkenes via direct transmetalation of arylboronic acids

    Y. Zhang, G. Chen and D. Zhao, Chem. Sci., 2019, Advance Article , DOI: 10.1039/C9SC02182E

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