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Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents

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Abstract

Isolation and characterization of stable radicals has been a long-pursued quest. While there has been some progress in this field particularly with respect to carbon, radicals involving heavier p-block elements are still considerably sparse. In this review we describe our recent successful efforts on the isolation of stable p-block element radicals particularly those involving aluminum, silicon, and phosphorus.

Graphical abstract: Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents

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Publication details

The article was received on 19 Mar 2019, accepted on 06 Apr 2019 and first published on 08 Apr 2019


Article type: Minireview
DOI: 10.1039/C9SC01351B
Citation: Chem. Sci., 2019, Advance Article
  • Open access: Creative Commons BY license
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    Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents

    S. Kundu, S. Sinhababu, V. Chandrasekhar and H. W. Roesky, Chem. Sci., 2019, Advance Article , DOI: 10.1039/C9SC01351B

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