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A ruthenium(II)-catalyzed C–H allenylation-based approach to allenoic acids

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Abstract

A Ru(II)-catalyzed direct access to various functionalized allenoic acids via C–H allenylation of readily available aryl carboxylic acids with propargylic acetates is reported. Axially chiral allenoic acids could be obtained in high ee by using optically active propargylic acetates through a chirality transfer strategy.

Graphical abstract: A ruthenium(ii)-catalyzed C–H allenylation-based approach to allenoic acids

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Publication details

The article was received on 02 Feb 2019, accepted on 04 May 2019 and first published on 10 May 2019


Article type: Edge Article
DOI: 10.1039/C9SC00603F
Chem. Sci., 2019, Advance Article
  • Open access: Creative Commons BY license
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    A ruthenium(II)-catalyzed C–H allenylation-based approach to allenoic acids

    X. Wu, J. Fan, C. Fu and S. Ma, Chem. Sci., 2019, Advance Article , DOI: 10.1039/C9SC00603F

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