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Issue 11, 2019
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Site-selective nitrenoid insertions utilizing postfunctionalized bifunctional rhodium(II) catalysts

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Abstract

We report a new strategy for the preparation of dirhodium(II) complexes with the general formula Rh2(A)4 that allows the isolation of a dirhodium tetracarboxylate complex with a free amino group available for postfunctionalization. The postfunctionalization of this complex enables the incorporation of a variety of functional groups, including double and triple bonds as well as nucleophilic moieties, thus paving the way to new classes of polymeric as well as bifunctional catalysts, and polymetallic complexes. Furthermore, we demonstrate that a urea containing dirhodium(II) complex enables site-selective nitrenoid insertions by remote hydrogen bonding control.

Graphical abstract: Site-selective nitrenoid insertions utilizing postfunctionalized bifunctional rhodium(ii) catalysts

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Publication details

The article was received on 21 Dec 2018, accepted on 05 Feb 2019 and first published on 06 Feb 2019


Article type: Edge Article
DOI: 10.1039/C8SC05733H
Chem. Sci., 2019,10, 3324-3329
  • Open access: Creative Commons BY-NC license
    All publication charges for this article have been paid for by the Royal Society of Chemistry

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    Site-selective nitrenoid insertions utilizing postfunctionalized bifunctional rhodium(II) catalysts

    J. Berndt, Y. Radchenko, J. Becker, C. Logemann, D. R. Bhandari, R. Hrdina and P. R. Schreiner, Chem. Sci., 2019, 10, 3324
    DOI: 10.1039/C8SC05733H

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