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Issue 11, 2019
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Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators

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Abstract

A hydrogenated frustrated Lewis pair ([TMPH+][HB(C6F5)3]) promotes controlled living ionic polymerization of cyanoacrylates. Controlled growth of various homopolymeric CAs through sequential monomer addition has been achieved, in addition to CA block copolymers with controlled block sequences for the first time in the long history of these materials.

Graphical abstract: Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators

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Publication details

The article was received on 23 Oct 2018, accepted on 30 Jan 2019 and first published on 01 Feb 2019


Article type: Edge Article
DOI: 10.1039/C8SC04729D
Citation: Chem. Sci., 2019,10, 3295-3299
  • Open access: Creative Commons BY-NC license
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    Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators

    R. Sáez, C. McArdle, F. Salhi, J. Marquet and R. M. Sebastián, Chem. Sci., 2019, 10, 3295
    DOI: 10.1039/C8SC04729D

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