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Polymorphism of nanocrystalline TiO2 prepared in a stagnation flame: formation of the TiO2-II phase

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Abstract

A metastable “high-pressure” phase known as α-PbO2-type TiO2 or TiO2-II is prepared via a single-step synthesis using a laminar premixed stagnation flame. Three other TiO2 polymorphs, namely anatase, rutile and TiO2-B phases, can also be obtained by tuning the oxygen/fuel ratio. TiO2-II is observed as a mixture with rutile under oxygen-lean flame conditions. To the best of our knowledge, this is the first time that this phase has been identified in flame-synthesised TiO2. The formation of TiO2-II in an atmospheric pressure flame cannot be explained thermodynamically and is hypothesised to be kinetically driven through the oxidation and solid-state transformation of a sub-oxide TiO2−x intermediate. In this scenario, rutile is nucleated from the metastable TiO2-II phase instead of directly from a molten/amorphous state. Mixtures containing three-phase heterojunctions of anatase, rutile, and TiO2-II nanoparticles as prepared here in slightly oxygen-lean flames might be important in photocatalysis due to enhanced electron–hole separation.

Graphical abstract: Polymorphism of nanocrystalline TiO2 prepared in a stagnation flame: formation of the TiO2-II phase

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Publication details

The article was received on 05 Jul 2018, accepted on 09 Nov 2018 and first published on 14 Nov 2018


Article type: Edge Article
DOI: 10.1039/C8SC02969E
Citation: Chem. Sci., 2019, Advance Article
  • Open access: Creative Commons BY license
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    Polymorphism of nanocrystalline TiO2 prepared in a stagnation flame: formation of the TiO2-II phase

    M. Y. Manuputty, J. A. H. Dreyer, Y. Sheng, E. J. Bringley, Maria L. Botero, J. Akroyd and M. Kraft, Chem. Sci., 2019, Advance Article , DOI: 10.1039/C8SC02969E

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