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Biomass-derived carbon supported Ni catalyst: An effective heterogeneous non-noble metal catalyst for the hydrogenation of nitro compounds

Abstract

There has been a great deal of attention in the development of heterogeneous non-noble metal catalysts for the selective and mild hydrogenation of nitro compounds into primary amines. Herein, the biomass-derived carbon material supported Ni catalyst (Ni/C) was facilely prepared by the one-pot pyrolysis process, and the as-prepared Ni/C catalyst demonstrated a high catalytic activity for the hydrogenation of nitro compounds into primary amines at room temperature. The Ni/C catalyst not only demonstrated a high catalytic activity, but also showed a good tolerance to other functional groups. Structurally-diverse primary amines were achieved in yields from 92% to 99% within a few hour at room temperature under 5 bar H2. Furthermore, the Ni/C catalyst showed a good reusability without the loss of its activity.

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Publication details

The article was received on 07 Sep 2019, accepted on 06 Nov 2019 and first published on 07 Nov 2019


Article type: Paper
DOI: 10.1039/C9RE00366E
React. Chem. Eng., 2019, Accepted Manuscript

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    Biomass-derived carbon supported Ni catalyst: An effective heterogeneous non-noble metal catalyst for the hydrogenation of nitro compounds

    Q. Tang, Z. Yuan, S. Jin, K. Yao, H. Yang, Q. Chi and B. Liu, React. Chem. Eng., 2019, Accepted Manuscript , DOI: 10.1039/C9RE00366E

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