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Ruthenium polypyridyl complex-catalysed aryl alkoxylation of styrenes: improving reactivity using a continuous flow photo-microreactor

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Abstract

Previously, we reported the ruthenium polypyridyl complex-catalysed aryl alkoxylation reaction of styrenes with aryldiazonium salts. In the developed reaction course, the instability of the diazonium salts caused poor product yields. In this context, we focused on the use of a continuous flow photo microreactor as a way to improve the efficacy of the aryl alkoxylation reaction. In this report, we describe an improved protocol for the aryl alkoxylation of styrenes catalysed by a ruthenium polypyridyl complex that relies on the use of a continuous flow photo microreactor.

Graphical abstract: Ruthenium polypyridyl complex-catalysed aryl alkoxylation of styrenes: improving reactivity using a continuous flow photo-microreactor

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Publication details

The article was received on 06 Feb 2019, accepted on 17 Apr 2019 and first published on 17 Apr 2019


Article type: Communication
DOI: 10.1039/C9RE00061E
React. Chem. Eng., 2019, Advance Article

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    Ruthenium polypyridyl complex-catalysed aryl alkoxylation of styrenes: improving reactivity using a continuous flow photo-microreactor

    E. Yamaguchi, N. Taguchi and A. Itoh, React. Chem. Eng., 2019, Advance Article , DOI: 10.1039/C9RE00061E

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