Issue 52, 2019
From the journal:

RSC Advances

Ir(iii)-catalyzed thioether directed arene C–H alkenylation†

Chen Li,a   Xian Chen,‡a   Rui-Peng Bao,‡b   Dong-Li Li,*a   Kun Zhanga  and  Dong-Hui Wang ORCID logo *b  

* Corresponding authors

a School of Biotechnology & Health Sciences, Wuyi University, 22 Dongcheng Vill., Jiangmen, Guangdong 529020, China
E-mail: wyuchemldl@126.com

b CAS Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Center for Excellence in Molecular Synthesis, University of Chinese Academy of Sciences, Shanghai Institute of Organic Chemistry, CAS, 345 Lingling Rd., Shanghai 200032
E-mail: Chinadhwang@sioc.ac.cn

Abstract

In this study, we demonstrate an Ir(III)-catalyzed thioether directed alkenylation of arene C–H bonds under mild reaction conditions. The selectivity for mono- or di-alkenylation is controlled by the concentration of alkene and oxidant loading. Various functional groups are tolerated, and moderate to good yields of alkenylated products are achieved.

Graphical abstract: Ir(iii)-catalyzed thioether directed arene C–H alkenylation

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Article information

DOI
https://doi.org/10.1039/C9RA06811B
Article type
Paper
Submitted
28 Aug 2019
Accepted
16 Sep 2019
First published
24 Sep 2019
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2019,9, 30134-30138

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Ir(III)-catalyzed thioether directed arene C–H alkenylation

C. Li, X. Chen, R. Bao, D. Li, K. Zhang and D. Wang, RSC Adv., 2019, 9, 30134 DOI: 10.1039/C9RA06811B

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