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Issue 51, 2019, Issue in Progress
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SO2F2 mediated cascade dehydrogenative Morita–Baylis–Hillman reaction of the C(sp3)–H of primary alcohols with the C(sp2)–H of electron-deficient olefins for the assembly of allylic alcohols

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Abstract

A cascade dehydrogenative Morita–Baylis–Hillman reaction of the C(sp3)–H of primary alcohols with the C(sp2)–H of electron-deficient olefins for forming allylic alcohols mediated by SO2F2 was developed. This method provides a mild process for the preparation of allylic alcohol moieties without the requirement of transition metals.

Graphical abstract: SO2F2 mediated cascade dehydrogenative Morita–Baylis–Hillman reaction of the C(sp3)–H of primary alcohols with the C(sp2)–H of electron-deficient olefins for the assembly of allylic alcohols

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Article information


Submitted
12 Jul 2019
Accepted
03 Sep 2019
First published
20 Sep 2019

This article is Open Access

RSC Adv., 2019,9, 29784-29787
Article type
Paper

SO2F2 mediated cascade dehydrogenative Morita–Baylis–Hillman reaction of the C(sp3)–H of primary alcohols with the C(sp2)–H of electron-deficient olefins for the assembly of allylic alcohols

Y. Jiang, N. S. Alharbi, B. Sun and H. Qin, RSC Adv., 2019, 9, 29784
DOI: 10.1039/C9RA05346H

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