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Issue 41, 2019
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tBuOK-triggered bond formation reactions

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Abstract

Recently, inexpensive and readily available tBuOK has seen widespread use in transition-metal-free reactions. Herein, we report the use of tBuOK for S–S, S–Se, N[double bond, length as m-dash]N and C[double bond, length as m-dash]N bond formations, which significantly extends the scope of tBuOK in chemical synthesis. Compared with traditional methods, we have realized mild and general methods for disulfide, azobenzenes imine etc. synthesis.

Graphical abstract: tBuOK-triggered bond formation reactions

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Supplementary files

Article information


Submitted
05 Jun 2019
Accepted
20 Jul 2019
First published
02 Aug 2019

This article is Open Access

RSC Adv., 2019,9, 24025-24029
Article type
Paper

tBuOK-triggered bond formation reactions

Y. Xu, X. Shi and L. Wu, RSC Adv., 2019, 9, 24025
DOI: 10.1039/C9RA04242C

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material and it is not used for commercial purposes.

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    [Original citation] - Published by The Royal Society of Chemistry.

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