Issue 40, 2019, Issue in Progress

Vinylpyrroles: solid-state structures and aggregation-induced emission properties

Abstract

An aggregation-induced emission chromophore, vinylpyrrole, was prepared from a formylpyrrole derivative, Meldrum's acid, and 1,3-dimethylbarbituric acid. The optical properties of the chromophore both in the solution and solid states were investigated by UV-vis and fluorescence spectroscopy. Single crystal X-ray diffraction measurements revealed that the dimethylbarbituric acid adduct formed a J-aggregate in the solid and resulted in higher fluorescence quantum yield compared to the Meldrum's acid adduct. Emission enhancement was found to occur by the restriction of molecular rotation in the solid state.

Graphical abstract: Vinylpyrroles: solid-state structures and aggregation-induced emission properties

Supplementary files

Article information

Article type
Paper
Submitted
30 May 2019
Accepted
16 Jul 2019
First published
23 Jul 2019
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2019,9, 22817-22822

Vinylpyrroles: solid-state structures and aggregation-induced emission properties

T. Okawara, Y. Matsufuji, K. Mizuno, K. Takehara, T. Nagamura and S. Iwasa, RSC Adv., 2019, 9, 22817 DOI: 10.1039/C9RA04088A

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