Issue 24, 2019
From the journal:

Organic Chemistry Frontiers

Copper-catalyzed nitrene transfer/cyclization cascade to synthesize 3a-nitrogenous furoindolines and pyrroloindolines†

Guang-Yi Zhang,a   Yi Peng,a   Jing Xue,a   Yan-Hui Fana  and  Qing-Hai Deng ORCID logo *a  

* Corresponding authors

a The Education Ministry Key Lab of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, P. R. China
E-mail: qinghaideng@hotmail.com

Abstract

An efficient copper-catalyzed nitrene transfer/cyclization of tryptophols and tryptamines was successfully developed. A series of 3a-nitrogenous indole alkaloids were obtained in good to excellent yields (up to 99%) using aryl azides as the nitrogen source.

Graphical abstract: Copper-catalyzed nitrene transfer/cyclization cascade to synthesize 3a-nitrogenous furoindolines and pyrroloindolines

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Article information

DOI
https://doi.org/10.1039/C9QO01124B
Article type
Research Article
Submitted
10 Sep 2019
Accepted
28 Oct 2019
First published
28 Oct 2019

Org. Chem. Front., 2019,6, 3934-3938

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Copper-catalyzed nitrene transfer/cyclization cascade to synthesize 3a-nitrogenous furoindolines and pyrroloindolines

G. Zhang, Y. Peng, J. Xue, Y. Fan and Q. Deng, Org. Chem. Front., 2019, 6, 3934 DOI: 10.1039/C9QO01124B

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