Jump to main content
Jump to site search

Issue 17, 2019
Previous Article Next Article

Co-Catalyzed decarbonylative alkylative esterification of styrenes with aliphatic aldehydes and hypervalent iodine(III) reagents

Author affiliations

Abstract

A convenient Co-catalyzed three-component decarbonylative alkylative esterification of styrene derivatives with aliphatic aldehydes and iodobenzene diacetate to provide chain elongated acetates and benzoates has been developed. Readily available aliphatic aldehydes are decarbonylated into 1°, 2° and 3° alkyl radicals for the construction of a C(sp3)–C(sp3) bond via radical addition and an interconversion of CoII–CoIII–CoI complexes is accountable for the formation of a C(sp3)–O bond.

Graphical abstract: Co-Catalyzed decarbonylative alkylative esterification of styrenes with aliphatic aldehydes and hypervalent iodine(iii) reagents

Back to tab navigation

Supplementary files

Publication details

The article was received on 10 Jun 2019, accepted on 08 Jul 2019 and first published on 09 Jul 2019


Article type: Research Article
DOI: 10.1039/C9QO00748B
Org. Chem. Front., 2019,6, 3065-3070

  •   Request permissions

    Co-Catalyzed decarbonylative alkylative esterification of styrenes with aliphatic aldehydes and hypervalent iodine(III) reagents

    Y. Peng, Y. Jiang, X. Du, D. Ma and L. Yang, Org. Chem. Front., 2019, 6, 3065
    DOI: 10.1039/C9QO00748B

Search articles by author

Spotlight

Advertisements