Issue 17, 2019
From the journal:

Organic Chemistry Frontiers

Co-Catalyzed decarbonylative alkylative esterification of styrenes with aliphatic aldehydes and hypervalent iodine(iii) reagents†

Yong Peng,a   Yuan-Yuan Jiang,a   Xue-Jiao Du,a   Da-You Mab  and  Luo Yang ORCID logo *a  

* Corresponding authors

a Key Laboratory for Environmentally Friendly Chemistry and Application of the Ministry of Education, Key Laboratory for Green Organic Synthesis and Application of Hunan Province, College of Chemistry, Xiangtan University, Hunan, PR China
E-mail: yangluo@xtu.edu.cn

b Xiangya School of Pharmaceutical Sciences, Central South University, Hunan 410013, PR China

Abstract

A convenient Co-catalyzed three-component decarbonylative alkylative esterification of styrene derivatives with aliphatic aldehydes and iodobenzene diacetate to provide chain elongated acetates and benzoates has been developed. Readily available aliphatic aldehydes are decarbonylated into 1°, 2° and 3° alkyl radicals for the construction of a C(sp3)–C(sp3) bond via radical addition and an interconversion of CoII–CoIII–CoI complexes is accountable for the formation of a C(sp3)–O bond.

Graphical abstract: Co-Catalyzed decarbonylative alkylative esterification of styrenes with aliphatic aldehydes and hypervalent iodine(iii) reagents

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Article information

DOI
https://doi.org/10.1039/C9QO00748B
Article type
Research Article
Submitted
10 Jun 2019
Accepted
08 Jul 2019
First published
09 Jul 2019

Org. Chem. Front., 2019,6, 3065-3070

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Co-Catalyzed decarbonylative alkylative esterification of styrenes with aliphatic aldehydes and hypervalent iodine(III) reagents

Y. Peng, Y. Jiang, X. Du, D. Ma and L. Yang, Org. Chem. Front., 2019, 6, 3065 DOI: 10.1039/C9QO00748B

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