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Bistrifluoromethylated organocuprate [Ph4P]+[Cu(CF3)2]: synthesis, characterization and its application for trifluoromethylation of activated heteroaryl bromides, chlorides and iodides

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Abstract

The synthesis and characterization of a bistrifluoromethylated organocuprate [Ph4P]+[Cu(CF3)2] and its reactions with a variety of activated heteroaryl bromides, chlorides and iodides were described. These results showed that complex [Ph4P]+[Cu(CF3)2] can serve as a trifluoromethylating reagent.

Graphical abstract: Bistrifluoromethylated organocuprate [Ph4P]+[Cu(CF3)2]−: synthesis, characterization and its application for trifluoromethylation of activated heteroaryl bromides, chlorides and iodides

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Publication details

The article was received on 18 Apr 2019, accepted on 11 May 2019 and first published on 13 May 2019


Article type: Research Article
DOI: 10.1039/C9QO00527G
Org. Chem. Front., 2019, Advance Article

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    Bistrifluoromethylated organocuprate [Ph4P]+[Cu(CF3)2]: synthesis, characterization and its application for trifluoromethylation of activated heteroaryl bromides, chlorides and iodides

    H. Liu and Q. Shen, Org. Chem. Front., 2019, Advance Article , DOI: 10.1039/C9QO00527G

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