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Copper-promoted dehydrogenative cross-coupling reaction of dialkyl phosphites with sulfoximines

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Abstract

An efficient method for the dehydrogenative cross-coupling of dialkyl phosphites with sulfoximines is demonstrated in the presence of copper(II) acetate and triethylamine. A library of sulfoximines including aryl, heteroaryl and alkyl sulfoximines underwent coupling reaction smoothly and gave the desired sulfoximine derived phosphoramidates in good to excellent yields.

Graphical abstract: Copper-promoted dehydrogenative cross-coupling reaction of dialkyl phosphites with sulfoximines

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Publication details

The article was received on 03 Apr 2019, accepted on 06 May 2019 and first published on 06 May 2019


Article type: Research Article
DOI: 10.1039/C9QO00469F
Org. Chem. Front., 2019, Advance Article

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    Copper-promoted dehydrogenative cross-coupling reaction of dialkyl phosphites with sulfoximines

    S. Gupta, S. Baranwal, P. Chaudhary and J. Kandasamy, Org. Chem. Front., 2019, Advance Article , DOI: 10.1039/C9QO00469F

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