Issue 9, 2019

Silver-catalyzed cascade radical cyclization of 2-(allyloxy)arylaldehydes with cyclopropanols: access to chroman-4-one derivatives

Abstract

A novel silver-catalyzed cascade radical cyclization of 2-(allyloxy)arylaldehydes with cyclopropanols was developed to synthesize carbonyl-containing alkyl-substituted chroman-4-one derivatives. This transformation is easy to conduct under mild oxidative conditions to generate two carbon–carbon bonds in a cascade radical sequence with a broad substrate scope.

Graphical abstract: Silver-catalyzed cascade radical cyclization of 2-(allyloxy)arylaldehydes with cyclopropanols: access to chroman-4-one derivatives

Supplementary files

Article information

Article type
Research Article
Submitted
23 Feb 2019
Accepted
17 Mar 2019
First published
18 Mar 2019

Org. Chem. Front., 2019,6, 1471-1475

Silver-catalyzed cascade radical cyclization of 2-(allyloxy)arylaldehydes with cyclopropanols: access to chroman-4-one derivatives

J. Sheng, J. Liu, L. Chen, L. Zhang, L. Zheng and X. Wei, Org. Chem. Front., 2019, 6, 1471 DOI: 10.1039/C9QO00292H

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