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Issue 9, 2019
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Catalyst-free oxidative N–N coupling for the synthesis of 1,2,3-triazole compounds with tBuONO

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Abstract

We disclose a catalyst-free method to synthesize 1,2,3-triazoles rapidly via an oxidative N–N coupling strategy. Of particular note is that the one-step synthesis route to access [1,2,3]triazolo[1,5-a]pyridines from pyridin-2-ylmethanamine has been reported for the first time. This approach features no use of catalyst, extremely mild conditions and excellent efficiency.

Graphical abstract: Catalyst-free oxidative N–N coupling for the synthesis of 1,2,3-triazole compounds with tBuONO

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Publication details

The article was received on 16 Jan 2019, accepted on 17 Mar 2019 and first published on 19 Mar 2019


Article type: Research Article
DOI: 10.1039/C9QO00071B
Citation: Org. Chem. Front., 2019,6, 1481-1484

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    Catalyst-free oxidative N–N coupling for the synthesis of 1,2,3-triazole compounds with tBuONO

    Y. Cai, X. Zhang, C. An, Y. Yang, W. Liu, W. Gao, X. Huang, Y. Zhou, M. Liu and H. Wu, Org. Chem. Front., 2019, 6, 1481
    DOI: 10.1039/C9QO00071B

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