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Reactions of 2-Aza-21-carbaporphyrin with Aniline Derivatives

Abstract

Regioselective azotization or bis(amination) products of the title porphyrinoid were achieved in one-pot one-step syntheses under mild conditions using selection of aromatic amines and isoamyl nitrite or p-chloranil, respectively. Structures, tautomery, chirality as well as spectroscopic and redox properties of the new systems were discussed.

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Publication details

The article was received on 07 Jan 2019, accepted on 11 Feb 2019 and first published on 12 Feb 2019


Article type: Research Article
DOI: 10.1039/C9QO00024K
Citation: Org. Chem. Front., 2019, Accepted Manuscript

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    Reactions of 2-Aza-21-carbaporphyrin with Aniline Derivatives

    D. Ren, B. Liu, X. Li, S. Koniarz, M. Pawlicki and P. J. Chmielewski, Org. Chem. Front., 2019, Accepted Manuscript , DOI: 10.1039/C9QO00024K

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