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Amidinium–carboxylate salt bridge mediated proton-coupled electron transfer in a donor–acceptor supramolecular system

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Abstract

A supramolecular polymer, 3T-DPP, that undergoes photoinduced proton-coupled electron transfer was constructed by means of amidinium-carboxylate salt bridges that serve to link terthiophene electron donors and diketopyrrolopyrrole electron acceptors with a 1 : 1 binding constant of 1.13 × 105 M−1 in N-methyl pyrrolidone.

Graphical abstract: Amidinium–carboxylate salt bridge mediated proton-coupled electron transfer in a donor–acceptor supramolecular system

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Publication details

The article was received on 25 Dec 2018, accepted on 22 Jan 2019 and first published on 24 Jan 2019


Article type: Research Article
DOI: 10.1039/C8QO01408F
Citation: Org. Chem. Front., 2019, Advance Article

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    Amidinium–carboxylate salt bridge mediated proton-coupled electron transfer in a donor–acceptor supramolecular system

    X. Ren, X. Wang, Y. Sun, X. Chi, D. Mangel, H. Wang and J. L. Sessler, Org. Chem. Front., 2019, Advance Article , DOI: 10.1039/C8QO01408F

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