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Synthesis of chiral seven-membered cyclic sulfonamides through palladium-catalyzed arylation of cyclic imines

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Abstract

An enantioselective palladium-catalyzed addition of arylboronic acids to seven-membered cyclic N-sulfonyl aldimines and ketimines has been developed, giving the chiral cyclic sulfonamides with excellent yields and up to 99% ee.

Graphical abstract: Synthesis of chiral seven-membered cyclic sulfonamides through palladium-catalyzed arylation of cyclic imines

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Publication details

The article was received on 08 Dec 2018, accepted on 20 Mar 2019 and first published on 22 Mar 2019


Article type: Research Article
DOI: 10.1039/C8QO01323C
Citation: Org. Chem. Front., 2019, Advance Article

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    Synthesis of chiral seven-membered cyclic sulfonamides through palladium-catalyzed arylation of cyclic imines

    Z. Zhao, L. Shi, F. Meng, Y. Li and Y. Zhou, Org. Chem. Front., 2019, Advance Article , DOI: 10.1039/C8QO01323C

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