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Issue 10, 2019
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Synthesis of chiral seven-membered cyclic sulfonamides through palladium-catalyzed arylation of cyclic imines

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Abstract

An enantioselective palladium-catalyzed addition of arylboronic acids to seven-membered cyclic N-sulfonyl aldimines and ketimines has been developed, giving the chiral cyclic sulfonamides with excellent yields and up to 99% ee.

Graphical abstract: Synthesis of chiral seven-membered cyclic sulfonamides through palladium-catalyzed arylation of cyclic imines

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Article information


Submitted
08 Dec 2018
Accepted
20 Mar 2019
First published
22 Mar 2019

Org. Chem. Front., 2019,6, 1572-1576
Article type
Research Article

Synthesis of chiral seven-membered cyclic sulfonamides through palladium-catalyzed arylation of cyclic imines

Z. Zhao, L. Shi, F. Meng, Y. Li and Y. Zhou, Org. Chem. Front., 2019, 6, 1572
DOI: 10.1039/C8QO01323C

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