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Nickel-promoted C(2)–H amidation of quinoline N-oxides with N-fluorobenzenesulfonimide

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Abstract

Reported herein is an unprecedented nickel-promoted C–H amidation reaction of quinoline N-oxides using N-fluorobenzenesulfonimide (NFSI) as the amination reagent. This strategy provides a convenient access to a variety of useful 1,2-dihydro-2-iminoquinolines in moderate to good yields. Notable advantages of this protocol include easy operation and mild reaction conditions.

Graphical abstract: Nickel-promoted C(2)–H amidation of quinoline N-oxides with N-fluorobenzenesulfonimide

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Publication details

The article was received on 27 Nov 2018, accepted on 01 Feb 2019 and first published on 05 Feb 2019


Article type: Research Article
DOI: 10.1039/C8QO01281D
Citation: Org. Chem. Front., 2019, Advance Article

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    Nickel-promoted C(2)–H amidation of quinoline N-oxides with N-fluorobenzenesulfonimide

    S. Han, X. Gao, Q. Wu, J. Li, D. Zou, Y. Wu and Y. Wu, Org. Chem. Front., 2019, Advance Article , DOI: 10.1039/C8QO01281D

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