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Solvent-tuned chemoselective carboazidation and diazidation of alkenes via iron catalysis

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Abstract

We have described Fe-catalyzed chemoselective oxidative carboazidation and diazidation of alkenes by employing CH2Cl2 as the chloromethyl source and TMSN3 as the azido source. For the synthesis, we have taken the advantage of solvent-controlled generation of C-based and N-based radicals, allowing the construction of molecularly diverse azido compounds from readily available starting materials through a simple operation.

Graphical abstract: Solvent-tuned chemoselective carboazidation and diazidation of alkenes via iron catalysis

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Publication details

The article was received on 22 Oct 2018, accepted on 26 Dec 2018 and first published on 27 Dec 2018


Article type: Research Article
DOI: 10.1039/C8QO01142G
Citation: Org. Chem. Front., 2019, Advance Article
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    Solvent-tuned chemoselective carboazidation and diazidation of alkenes via iron catalysis

    L. Xu, J. Chen and L. Chu, Org. Chem. Front., 2019, Advance Article , DOI: 10.1039/C8QO01142G

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