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Anion–π and anion–π-radical interactions in bis(triphenylphosphonium)-naphthalene diimide salts

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Abstract

We have conducted a systematic study of anion–π and anion–π-radical interactions in bis(triphenylphosphonium)-naphthalene diimide (BTPP-NDI) salts which was made possible with the synthesis of different anionic analogues. DFT calculations and experimental evidence show anion–π and anion–π-radical interactions and that the cationic π-radical can induce magnetic spin polarization of the anion.

Graphical abstract: Anion–π and anion–π-radical interactions in bis(triphenylphosphonium)-naphthalene diimide salts

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Publication details

The article was received on 17 Oct 2018, accepted on 20 Nov 2018 and first published on 21 Nov 2018


Article type: Research Article
DOI: 10.1039/C8QO01122B
Citation: Org. Chem. Front., 2019, Advance Article
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    Anion–π and anion–π-radical interactions in bis(triphenylphosphonium)-naphthalene diimide salts

    C. K. Ng, T. L. D. Tam, F. Wei, X. Lu and J. Wu, Org. Chem. Front., 2019, Advance Article , DOI: 10.1039/C8QO01122B

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