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Facile synthesis of diverse rotaxanes via successive supramolecular transformations

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Abstract

Facile synthesis of diverse rotaxanes was successfully realized through a simple and efficient supramolecular transformation strategy. Starting from an organometallic [3]rotaxane with a platinum-acetylide moiety as the bridge moiety and transformation site, employing a simple phosphine ligand exchange and sequential reductive elimination reactions resulted in the successful preparation of various rotaxanes with diverse structures and properties.

Graphical abstract: Facile synthesis of diverse rotaxanes via successive supramolecular transformations

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Publication details

The article was received on 01 Jul 2019, accepted on 05 Sep 2019 and first published on 06 Sep 2019


Article type: Research Article
DOI: 10.1039/C9QM00430K
Mater. Chem. Front., 2019, Advance Article

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    Facile synthesis of diverse rotaxanes via successive supramolecular transformations

    Y. Hu, W. Wang, R. Yao, X. Wang, Y. Wang, B. Sun, L. Chen, Y. Zhang, X. Zhao, L. Xu, H. Tan, Y. Yu, X. Li and H. Yang, Mater. Chem. Front., 2019, Advance Article , DOI: 10.1039/C9QM00430K

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