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Evidencing under-barrier phenomena in a Yb(iii) SMM: a joint luminescence/neutron diffraction/SQUID study

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Abstract

We report the synthesis, spectroscopic and magnetic characterisation and ab initio investigation of a new mononuclear ytterbium based complex, [YbTp2NO3], and discuss the physical mechanisms underlying the slow relaxation of its magnetisation in a moderate static field and at low temperature.

Graphical abstract: Evidencing under-barrier phenomena in a Yb(iii) SMM: a joint luminescence/neutron diffraction/SQUID study

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Publication details

The article was received on 17 Jun 2019, accepted on 06 Sep 2019 and first published on 10 Sep 2019


Article type: Research Article
DOI: 10.1039/C9QI00726A
Inorg. Chem. Front., 2019, Advance Article

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    Evidencing under-barrier phenomena in a Yb(III) SMM: a joint luminescence/neutron diffraction/SQUID study

    F. Guégan, J. Jung, B. Le Guennic, F. Riobé, O. Maury, B. Gillon, J. Jacquot, Y. Guyot, C. Morell and D. Luneau, Inorg. Chem. Front., 2019, Advance Article , DOI: 10.1039/C9QI00726A

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