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Three-dimensional hollow reduced graphene oxide spheres with a hierarchically porous structure for high-performance lithium–sulfur batteries

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Abstract

Herein, a three-dimensional hollow reduced graphene oxide (HrGO) with a hierarchically porous structure was successfully synthesized to load sulfur, where the sulfur loading could reach as high as 91.4 wt%. This stable structure was obtained by the chemical-assisted reduction of oxygen-containing groups and polyvinyl pyrrolidone, removal of silica templates, and freeze drying. Owing to the hierarchical pores and doped nitrogen in HrGO, the HrGO-supported sulfur (HrGO/S) cathode exhibited superior electrochemical performance with high rate capacity and long cycling life. HrGO/S with the sulfur content of 84.43 wt% delivered the high specific capacity of 863 mA h g−1 at the high current rate of 2C with coulombic efficiency greater than 99.5% and maintained the reversible capacity of 463 mA h g−1 after 600 cycles, corresponding to the capacity decay of 0.077% per cycle. Even when the sulfur content was as high as 91.4 wt%, HrGO/S still exhibited the specific capacity of 810 mA h g−1 at 2C. The hierarchically porous structure and doped nitrogen synergistically rendered HrGO a promising host material for lithium–sulfur batteries.

Graphical abstract: Three-dimensional hollow reduced graphene oxide spheres with a hierarchically porous structure for high-performance lithium–sulfur batteries

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Publication details

The article was received on 04 Jun 2019, accepted on 27 Jul 2019 and first published on 29 Jul 2019


Article type: Research Article
DOI: 10.1039/C9QI00656G
Inorg. Chem. Front., 2019, Advance Article

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    Three-dimensional hollow reduced graphene oxide spheres with a hierarchically porous structure for high-performance lithium–sulfur batteries

    M. Li, Y. Dai, X. Pei and W. Chen, Inorg. Chem. Front., 2019, Advance Article , DOI: 10.1039/C9QI00656G

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